Atomic Theory : Atomic Theory Atoms are incredibly small!
What we know about them is based on indirect evidence.
History of atomic theory : History of atomic theory 500 BC Democritus proposed idea of atom-but he had no experimental data to support it.
1800 Dalton proposed an atomic theory supported by experimental data.
Dalton’s Atomic theory : Dalton’s Atomic theory Support for his theory came when he began looking at the masses of elements that combined with eachother.
He found that elements combine in simple ratios by mass.
Dalton’s atomic theory : Dalton’s atomic theory Dalton’s atomic theory
all matter is composed of tiny, indivisible particles called atoms.
All atoms of the same element are identical.
Atoms can neither be created nor destroyed.
Atoms of two or more different elements can combine in small whole number ratios to form compounds.
Dalton’s atomic theory : Dalton’s atomic theory 2 problems with his theory:
Atoms of the same element have different masses
atoms have subatomic particles (electrons, protons and neutrons) So Dalton’s theory is not completely correct.
The Subatomic particles : The Subatomic particles MASS Charge
The subatomic particles : The subatomic particles Electron discovered ~1900 by JJ Thomson using his cathode ray tube.
Electron charge found by American Robert Millikan ~1910. Oil drop experiment
Proton found using adaptation of cathode ray tube ~1900.
Neutron discovered in 1932 by Chadwick.
Rutherford’s Gold Foil Experiment : Rutherford’s Gold Foil Experiment A consequence of the plum pudding model was that the atom would have a weak positive charge.
Rutherford tested this idea by firing positively charged particles at gold foil.
He expected particles to pass through.
His results surprised him.
Results of Gold Foil Experiment : Results of Gold Foil Experiment Atom is mostly empty space.
Protons are found in a dense nucleus in the center of the atom.
Problems with Rutherford’s model : Problems with Rutherford’s model Could not explain why electrons would not spiral into the nucleus.
Atoms to Elements : Atoms to Elements What makes elements different from one another?
The number of protons, electrons and neutrons in them.
C has 6 protons, 6 neutrons and 6 electrons, while H has 1 proton, 0 neutrons and 1electron.
Atomic number : Atomic number Atomic number: the number of protons in an atom.
Because atoms are neutral we know that protons must equal electrons and so atomic number is also equal to the number of electrons. Atomic number also equals the number of electrons in the neutral atom
How many protons in these atoms? How many electrons? : How many protons in these atoms? How many electrons? H
He
Li
Be
B
F
Ne
Mass number : Mass number Mass number- the total number of neutrons and protons in an atom.
If we know the mass number and the atomic number we can find the number of neutrons in an atom. Mass number - atomic number = number of neutrons
How many neutrons? How many electrons : How many neutrons? How many electrons Atomic number Mass number
Notation : Notation Atomic Number Mass Number
Another notation : Another notation Cu-65 Mass number
Isotopes : Isotopes Isotopes- elements with same number of protons and electrons, but different numbers of neutrons.
For example: How many protons, neutrons and electrons does each Isotope have?
Isotopes : Isotopes Mass #
FAQ: Average Atomic Masses : FAQ: Average Atomic Masses “If protons and neutrons weigh 1amu, then how come the periodic table has atomic masses with decimals? How does this happen?”
for example: the 2 isotopes of copper weigh 65 and 63amu’s. In periodic table it says 63.55amu.
Average atomic masses : Average atomic masses The average atomic mass is an average of the masses of the isotopes of an element.
The average atomic mass of Cu is an average of the two masses of the isotopes: 65amu and 63amu.
It’s a weighted average that takes into account the relative abundance of each isotope.
Atoms and ions : Atoms and ions Atoms are electrically neutral because they have equal numbers of protons and electrons.
EXAMPLE: Hydrogen has 1proton and 1 electron. They cancel eachother. • Atoms can gain or lose electrons when they
form compounds.
• When atoms lose or gain electrons they become
charged.
• Atoms having a positive or negative charge are
called ions.
Atoms and ions : Atoms and ions Sodium, Na, loses an electron when it forms NaCl. How many electrons in Na?
Atoms and ions : Atoms and ions Na 23 11 Sodium has atomic number 11,
meaning it has 11 protons and if
it is neutral it should have 11
electrons.
11 protons + 11electrons = 0 charge
So how many electrons would
Sodium have if it lost an electron?
Atoms and ions : Atoms and ions Na 23 11 If Sodium lost one electron it
would still have 11 protons, but
now it would have 10 electrons.
11 protons + 10 electrons = +1 charge We write the positively charged ion,
or cation, as Na+
Atoms and ions : Atoms and ions Cl 35 17 Chlorine gains an electron when it
forms compounds.
How many electrons does chlorine
have?
Atoms and ions : Atoms and ions Cl 35 17 Chlorine has atomic number 17,
meaning it has 17 protons and if
it is neutral it should have 17
electrons.
17 protons + 17electrons = 0 charge
So how many electrons would
Chlorine have if it gained an electron?
Atoms and ions : If chlorine gained one electron it
would still have 17 protons, but
now it would have 18 electrons.
17 protons + 18 electrons = -1charge Atoms and ions Cl 35 17 We write the negatively charged ion,
or anion, as Cl-
Write the symbol and name of the ion formed: : Write the symbol and name of the ion formed: A. Strontium atom loses two electrons
B. Iodine atom gains one electron
C. Magnesium atom loses two electrons
D. Oxygen atom gains two electrons
Complete the table : Complete the table