GCSE Additional Science June 2007 FT Chemistry paper

RD*(240-01) WELSH JOINT EDUCATION COMMITTEE CYD-BWYLLGOR ADDYSG CYMRU General Certificate of Secondary Education Tystysgrif Gyffredinol Addysg Uwchradd 240/01 ADDITIONAL SCIENCE FOUNDATION TIER (Grades G-C) CHEMISTRY 2 A.M. WEDNESDAY, 13 June 2007 (45 minutes) ADDITIONAL MATERIALS In addition to this paper you may require a calculator. INSTRUCTIONS TO CANDIDATES Write your name, centre number and candidate number in the spaces at the top of this page. Answer all questions. Write your answers in the spaces provided in this booklet. INFORMATION FOR CANDIDATES The number of marks is given in brackets at the end of each question or part-question. You are reminded of the necessity for good English and orderly presentation in your answers. The Periodic Table is printed on the back cover of the examination paper and the formulae for some common ions on the inside of the back cover. No certificate will be awarded to a candidate detected in any unfair practice during the examination. Candidate Name Centre Number Candidate Number For Examiner’s use only Total Marks2 Examiner only Arholwr yn unig (240-01) Answer all questions. 1. A fluorine atom can be represented by 6 (i) Use the numbers in the box below to answer this question. F 19 9 Each number can be used once, more than once or not at all. Complete the following sentences. I. Fluorine has . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . protons. [1] II. The atomic number of fluorine is . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [1] III. The mass number of fluorine is . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [1] IV. Fluorine has . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . neutrons. [1] (ii) Tick (!) the box next to the correct statement. I. An atom of fluorine has no charge, a positive charge, a negative charge. [1] II. An electron has a charge of +1, 0, –1. [1] 1 7 9 10 11 193 Examiner only Arholwr yn unig 2. (i) Complete the following table by stating whether the substance is a metal, non-metal or a compound. [4] Substance aluminium diamond graphite water vapour Structure Substance Metal, non-metal or compound aluminium diamond graphite water vapour (ii) Draw lines to connect each substance to its correct structure. [4] 8 (240-01) Turn over.4 Examiner only Arholwr yn unig (240-01) 3. (i) Most of the tap water in the UK comes from mountain reservoirs. The water from these reservoirs is never pure. It often contains • solids such as sand, mud and twigs, • dissolved substances such as nitrates from soil and calcium compounds from rocks, • tiny living organisms, such as bacteria. Before the water is safe to drink it must be treated. The following flow chart shows stages in a water treatment process. mountain reservoir filtration sedimentation users chlorination storage I. At which stage are the solid impurities removed? [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . II. State the reason for chlorination. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Examiner only Arholwr yn unig 5 I. Use the table above to label the pie chart below. Two labels have been added for you. [2] II. In very dry weather, we need to save water. State the first action a person would be advised to take by the Local Authority in order to save water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ii) In the UK, it has been estimated that each person uses about 180 litres of water every day. The following table shows how water is used by a person living in the UK. Use of water Litres toilet flushing personal washing washing clothes/dishes gardening cooking/drinking 72 36 40 18 14 (240-01) Turn over. gardening washing clothes/dishes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Examiner only Arholwr yn unig 4. This question is about the reactivity of metals. (i) A teacher carried out the following two experiments in a fume-cupboard. Experiment 1. A mixture of aluminium powder and iron oxide was heated strongly using the equipment shown. The reaction that took place can be summarised by the following word equation. aluminium + iron oxide aluminium oxide + iron (240-01) mixture of aluminium and iron oxide Heat Experiment 2. The above experiment was then repeated using a mixture of iron powder and copper oxide. The word equation for this reaction is shown below. iron + copper oxide iron oxide + copper Use the results of the two reactions to place the three metals aluminium, copper and iron in order of decreasing reactivity. [2] most reactive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . least reactive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 Examiner only Arholwr yn unig (ii) Zinc is more reactive than copper. Excess zinc powder was added to blue copper sulphate solution. During the reaction the blue solution became colourless and a brown solid was formed. I. Name the colourless solution A. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . II. Name the brown solid B. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 zinc powder start finish blue copper sulphate solution colourless solution A (240-01) Turn over. brown solid B8 Examiner only Arholwr yn unig 5. Ammonia, NH3, was first made commercially over a hundred years ago by a German scientist called Fritz Haber. He succeeded in reacting two elements to make the gas ammonia by a reversible reaction. (i) Use the formula shown above to name the two elements that Fritz Haber reacted together to make ammonia. [2] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . and . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (ii) Ammonia can be converted into two fertilisers, ammonium nitrate and ammonium sulphate. Ammonia is converted into ammonium nitrate by reacting with nitric acid. Name the acid used to convert ammonia into ammonium sulphate. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iii) Farmers often use fertilisers on their fields. There are two types of fertilisers – natural and man-made fertilisers. The following table shows the average yield of wheat and potatoes produced by a farmer in one year, using no fertiliser and a variety of fertilisers. Type of fertiliser none natural man-made fertiliser A man-made fertiliser B man-made fertiliser C Average yield of wheat /tonnes Average yield of potatoes /tonnes 0.5 7.2 6.8 7.5 4.9 8.0 31.9 24.5 25.9 9.1 (240-01)9 Examiner only Arholwr yn unig Use the information in the table to answer parts I. and II. 7 I. State the best fertiliser for growing wheat. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . II. State the best fertiliser for growing potatoes. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iv) Give two advantages of using fertilisers. [2] 1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (240-01) Turn over.10 Examiner only Arholwr yn unig (240-01) 5 6. (i) Polyvinylchloride (PVC) is an example of a polymer. Name two other polymers. [2] 1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (ii) The following list gives some properties of PVC. • strong • light • resistant to weathering • non toxic • does not conduct electricity • good thermal insulator Use only the properties in the above list to answer parts I., II. and III. Give the main reason for using PVC in I. blood storage bags, [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . II. window frames, [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . III. cable-coverings for electric blankets. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11 BLANK PAGE (240-01) Turn over.12 (240-01) 7. Potassium nitrate dissolves in water to form a solution. The table below shows the maximum mass of potassium nitrate that can dissolve in 100 g of water at different temperatures. The maximum mass of solid that can dissolve in 100 g of water is called the solubility of a substance. (i) Plot the points on the grid opposite and draw a smooth curve through them. Two points have been plotted for you. [3] Examiner only Arholwr yn unig Temperature /°C Solubility of potassium nitrate /g per 100 g of water 0 10 20 30 40 50 13 21 32 47 64 84 (ii) Use the graph to find the solubility of potassium nitrate at 35 °C. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . g per 100 g of water. (iii) Calculate the mass of potassium nitrate crystals that would form when a solution containing 64 g of potassium nitrate in 100 g of water was cooled to 20°C. [2] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13 Examiner only Arholwr yn unig (240-01) 6 Turn over. solubility of potassium nitrate /g per 100 g of water 0 10 20 30 40 50 60 0 10 20 30 40 50 60 70 80 90 100 temperature /°C14 8. Nitinol (NiTi) is an example of a shape memory alloy which was first developed in 1962-63. (i) Name the two metals present in this alloy. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . and . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (ii) State which of the following, A, B, C, D or E, best represents the structure of solid nitinol. [1] Examiner only Arholwr yn unig A B C D E The structure of nitinol is best represented by . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iii) Give one use of nitinol. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iv) State the special property that nitinol has compared with other alloys or metals. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 (240-01)15 Examiner only Arholwr yn unig 9. The following diagram shows how aluminium is extracted from its ore. (i) Give the name of the process used in the extraction of aluminium. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (ii) Give the name of the electrolyte used in this extraction. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iii) The word equation for the overall reaction that takes place during the extraction is shown below. aluminium oxide aluminium + oxygen During the reaction, reduction takes place. Use the above word equation to explain the meaning of the term reduction. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (iv) The extraction of aluminium from its ore uses large amounts of electricity and is therefore very expensive. State one method of reducing the cost of aluminium metal. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (v) Aluminium is a very good conductor of electricity and has a low density. Give one use of aluminium which relies on both of these properties. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . molten aluminium oxide oxygen aluminium (240-01) 5 Turn over.16 BLANK PAGE 240-01)17 BLANK PAGE 240-01) Turn over.18 BLANK PAGE 240-01)19 FORMULAE FOR SOME COMMON IONS POSITIVE IONS Name Formula NEGATIVE IONS Name Formula Aluminium Al3+ Ammonium NH + Barium Ba2+ Calcium Ca2+ Copper(II) Cu2+ Hydrogen H+ Iron(II) Fe2+ Iron(III) Fe3+ Lithium Li+ Magnesium Mg2+ Nickel Ni2+ Potassium K+ Silver Ag+ Sodium Na+ Bromide Br– Carbonate CO 2– Chloride Cl – Fluoride F– Hydroxide OH– Iodide I – Nitrate NO – Oxide O2– Sulphate SO 2– 4 433 Turn over. (240-01)20 Helium Neon Fluorine Chlorine Bromine Selenium Boron Aluminium Gallium Zinc Copper Nickel Cobalt Iron Manganese Chromium Vanadium Titanium Scandium Calcium Potassium Magnesium Sodium Beryllium Lithium Arsenic Phosphorus Nitrogen Carbon Silicon Germanium Sulphur Oxygen Argon Krypton 42 Ne 20 10 F 19 9 O 16 8 C 12 6 N 14 7 B 11 5 Ar 40 18 S 32 16 P 31 15 Si 28 14 Al 27 13 Kr 84 36 Br 80 35 Se 79 34 As 75 33 Ge 73 32 Ga 70 31 Zn 65 30 Cu 64 29 Ni 59 28 Fe 56 26 Co 59 27 Mn 55 25 V 51 23 Cr 52 24 Ti 48 22 Sc 45 21 Ca 40 20 K 39 19 Iodine Tellurium Indium Cadmium Silver Palladium Rhodium Ruthenium Molybdenum Niobium Zirconium Yttrium Strontium Rubidium Antimony Tin Xenon Xe 131 54 I 127 53 Te 128 52 Sb 122 51 Sn 119 50 In 115 49 Cd 112 48 Ag 108 47 Pd 106 46 Ru 101 44 Rh 103 45 Tc 99 43 Nb 93 41 Mo 96 42 Zr 91 40 Y 89 39 Sr 88 38 Rb 86 37 Astatine Polonium Thallium Mercury Gold Platinum Iridium Osmium Rhenium Tungsten Tantalum Hafnium Lanthanum Barium Caesium Bismuth Lead Radon Rn 222 86 At 210 85 Po 210 84 Bi 209 83 Pb 207 82 Tl 204 81 Hg 201 80 Au 197 79 Pt 195 78 Os 190 76 Ir 192 77 Re 186 75 Ta 181 73 W 184 74 Hf 179 72 La 139 57 Ba 137 56 Cs 133 55 Actinium Radium Francium Ac 227 89 Ra 226 88 Fr 223 87 Mg 24 12 Na 23 11 Be 94 Li 73 Hydrogen H 11 1 2 3 0 5 6 7 4 Group PERIODIC TABLE OF ELEMENTS He Cl 35 17 Z X AName Element Symbol Atomic number Mass number Key: Technetium (240-01)